Interesting question. A double san tee (DST) isn't against code per se, but it does go against the installation instructions of toilet manufacturers for back to back toilet installations. The reason is that the sudden dump of a lot of toilet water will skip across the DST and push water up the bowl of the opposite toilet and consequently lower the water level in that toilet.
I don't know if the same problem exists if a toilet 20ft away draining down that same side branch would skip across the tee. The waste may have slowed down by that point. Hard to know.
Butt I get the feeling your issue isn't so much that your new toilet is draining down that DST, but that you want to know that if you're already opening up the concrete for a bathroom installation in the slab, would it make sense to get rid of the DST... I would. Plus it would be a good time to get rid of that funky transition between ABS and PVC that were glued together..