Mineral deposits, rust particles, organic material could all contribute to that sludge especially if you have a leak and the autofill valve keeps adding water. The impeller from the circulator could also contribute to that or the insides of the boiler itself (more so with a CI heat exchanger rather than aluminum or SS). Water, if it's not being lost and replaced, reaches an equilibrium in a closed system, otherwise, the mineral content, and reactivity of the water can stay high.





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