Here's some background, alternety: My system was installed five years ago, uses PEX tubing without an oxygen barrier so it employs non-ferrous materials. It's stapled to the subfloor with a 1 1/2" gypcrete cover and insulated below, although several rooms of the house are on a slab so it's imbeded in the slab there. I have 14 zones with thermostats and I also have four central heating/AC units (six zones) and can use central heating to heat the house quickly such as when we return from a trip and have turned the radiant system down low.
Regarding your comment about mixing DHW with radiant heat water, I assume that Jim D's recommendation to use an indirect tank would ensure that the two were kept separate. Am I correct on that?
Bob
An indirect does not mix any of the boiler water with the potable water...it is heated by an internal hot water coil fed by the boiler - just like another zone on the boiler. As noted, this gives you more hot water faster since your system can dedicate the entire boiler's capacity to it if on a priority circuit (which momentarily disables the room heating pump). If you pick one with SS like the SuperSTor Ultra, it should be the last tank you ever buy. Because you don't have a super hot burner or element, you don't get the calcium deposits in it as much, either.
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Jim DeBruycker
Important note - I'm not a pro
Thanks, Jim D, I think I understand the indirect tank but... Tell me more about the outside reset valve. Am I correct in assuming that an outside reset valve would be of little value for me because a) my in-floor radiant system's water temperature should never be hotter than about 130 degrees and b) the winters where I live are mild, with lowest lows in the mid-20's?
Bob
The outside reset is not a valve, it is an input to the boiler controller. It "resets" the control, telling it what is needed based on the outside temperature...the colder it is, the more likely it needs a higher temperature. The best comfort is when you run the system constantly. The outside reset would tell the system when it doesn't need the water at 130, for example, and on a mild day may run it constantly at say 100, verses 130. Add that to a modulating boiler which gets more efficient at lower temperatures, and yes, it is actually more useful there.
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Jim DeBruycker
Important note - I'm not a pro
Jim, Bob...
I just fired one up today...wall mount buderus gb-142.
Bob...after seeing what you've typed so far (and boy there's alot to read).
You have 14 zones...how many square feet?
Bottom line...you sound like the perfect candidate for what Jims saying...which is exactly what I fired up today.
It's a little frustrating to go over and over the details...though I understand you want to know your options, the most efficient potential you have is this one.
I have done a good dozen or so tankless water heaters in the last couple of years...they run at the low to mid 80% AFUE (beats standard tank types at 60-65%), where condensing boilers get better than 90% and cover the heat also.
Beware...the "sticker price" will bowl you over...especially where it's not a "switch-out" boiler install. (same dimensions...same style boiler...easier install).
Also, if you have natural gas, you might be eligible for a substantial rebate - call them.
The outside temperature sensor that Jim mentioned simply helps the unit to run more efficiently in the summer months by letting it know to ease back on btu consumption...i.e. the indirect water heater takes less energy to reheat.
Grumpy Plumber
I was surprised at the number of controlled zones you have. I kind of related hot water heater powered and shared heating and DHW water with single or a small number of zones. How are you controlling the many zones in your house? One circulator and lots of solenoid valves or many pumps? You also indicate that there are differences in the thermal characteristics in some floors. In the slab on grade areas, did you insulate under the slab (you should have)? If you are using a fixed speed circulating pump and controlling zones with valves, you need to have a pressure bypass in the system. There are variable speed circulators with built-in pressure sensors becoming available that could eliminate the need for the bypass (my preferred solution). Also needs an expansion tank in the system.
If you have a situation where small zones can call for heat you may want a buffer tank to isolate the heat demand from running the boiler. This prevents short cycling of the boiler (bad for the boiler, and lowers efficiency). The demand is satisfied from the buffer tank. When the buffer tank water drops below a certain point the boiler recharges it.
Anyway, for as much as you have going in this system you should look into a smart control system. This type of system will learn the characteristics of a zone and provide the best operating conditions. It will know how much energy to pump into a zone to get it to the correct temperature without overheating (within limits caused by such things as sunlight and rapid outdoor changes). It will control the pumps and valves. It integrates everything. The outdoor reset, DHW, exercising the pumps and valves when they are not used enough to keep them limber, adjusting the temperature of the circulating water. Everything. They are expensive. My choice would be equipment from Tekmar. They have a lot of information on their web site. They will replace some of the smarts that will probably be built into the modulating boiler.
Of course, if you are happy with the way it works now, you can just stick in a new boiler. But I would do an indirect DHW tank.
This whole thing also serves as a warning about asking what you feel is a simple question. 
Alternety