PE is great stuff. I love it and use it whenever possible outside and in wells. The fittings are crap and hose clamps do not seal evenly.
California has hardly any unions compared to the east coast. Like the Texans, we can still carry our guns in town as long as in plain sight. Would not try it in LA however.... And we use PVC and PE all the time outside, and down wells.
PVC is a toxic waste in my opinion - bad chemistry and explodes when frozen, BUT its cheap for big diameters and great for non potable uses and conduit.
PEX is just crosslinked PE - its molecular structure is lined up in better order. It's just the next generation plastic with far better engineered fittings.
CPVC does not essentially exist any more far as I can tell, big lawsuit about the fittings years ago.
Rancher, I recall your post about the dual use well pump system. Good idea, I recently drilled a 60 foot well with water at 10' and 60 gpm [extraordinarily rare in this area] and plan to set a submersible and hand pump. You can still get a great hand made hand pump from the Pennsylvania Amish -brass and cast iron - if you look hard enough online. If I wasn't in a valley under the pines, I would do a windmill also.