http://www.copper.org/copperhome/DIY/************_solderingschool.html said:
7. HEATING
Begin heating with the flame perpendicular to the tube. The copper tube conducts the initial heat into the fitting cup for even distribution of heat in the joint area. The extent of this preheating depends upon the size of the joint. Preheating of the assembly should include the entire circumference of the tube in order to bring up to a suitable preheat condition. However, for joints in the horizontal position, avoid directly preheating the top of the joint to avoid burning the soldering flux. Practice and experience will indicate the amount of heat and time needed.
Next, move the flame onto the fitting cup. Sweep the flame alternately between the fitting cup and the tube a distance equal to the depth of the fitting cup. Again, preheating the circumference as described above, with the torch at the base of the fitting cup. Touch the solder to the joint If the solder does not melt, remove it and continue heating.