I'm not positive, hopefully someone else will have more experience than I do...
But I think you can drain one zone by shutting off all zones, then opening the drain and the plug in the bottom of the control valve. This should let water drain out of that zone, the other 2 control valves/shutoff valves should stop it from backflowing out of those zones. You'll only lose a little out of the boiler side b/c of the riser right before the zone breakdowns, unless you get a crazy siphon going, but I think having both of those locations open on the zone you're draining will stop a major siphon from occurring.
Be sure to turn off the boiler and the feeder first, and have a plan for how you're going to close off the control valve end of the system so you can get it done quickly and get your system up and running again. If it happens to be the zone with the union, that would make things easier...





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