when you say brass fittings do you mean cast copper fittings? (copper water fittings that look like brass)
what size pipe are you trying to solder
what type of flux
typically you put the heat at the end of the fitting socket away from the copper tube, when the solder melts it sucks in towards the heat, if you are heating at the visible joint the copper will over heat and the solder will roll off and not suck in





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