IF, and that can be a big IF, the boiler has a good, working, air extraction system and doesn't leak (as indicated by needing to refill it with water), then the water inside of the pipes is now fairly inert - any rusting that would have happened, has already happened, since with no leaks, or new water being added, there's none left to react with anything. Probably within the first week or two, the oxygen that might have been trapped in the water would react with the iron, and all the rust that could form, has formed, and it stops - no more corrosion can occur without additional oxygen. Same with anything else that might have been in the water, chlorine, etc., once it reacts with the metals there, there's nothing left in the water. Then, other than erosion from the water moving through (and that is minimal if the system was designed properly), it could last for a very long time.
So, what you have could be in great shape, or it could be about to spring leaks everywhere. If it is tight, and you don't refill, it's probably okay.
Repiping with say pex might allow you to gain some room, since the tubing could be run more like wire rather than rigid pipe, but probably isn't worth the effort unless you have problems now. My unprofessional opinion...





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