It sounds lke you may have over heated them...I would bring them back to the big box store if that s where you bought them... their policy is you can return them for any reason at all. The next time you do it you need to heat the fitting qiuckly, apply the solder, then try cooling it quickly with a wet cloth. This will help protect the inside of the valve...
Better still just do your work with the water off then turn it on when you are finished.
Don't even mess with the valve.





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