I'm not a plumber (actually I'm an electrician), but I can tell you this:
A union and a nipple are not the same (ok, that was easy).
In order to prevent the "galvonic reaction"(oxidation) between the dissimilar metals, you need either a di-electric break(plastic washer or some other non-conductive element) or a metal that does not contribute to the galvonic reaction, such as brass.
What is the nipple made of?





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