Take the bottom and top off a #10 can and split it so that you have a flat piece of metal. This works pretty well as a cheap way to protect from fire. Do have a spray bottle of water handy just in case. As noted, clean the pipe end and the inside of the fitting well, apply plenty of flux. Bend your solder so that you can reach around to the backside of the joint. Heat the joint until the solder flows, then bring the solder around the joint. Solder will flow into the joint if it's well fluxed and if you can get your solder around most of the fitting. I tend to use a bit more solder than probably necessary on joints like this just to be sure.