I'm no "pro" (as is proved by all my postings

), but what I have learned in the past 200 or so joints seems obvious NOW...LOL...heat the fitting, don't try and heat it in one second - take a little time and just heat it (MAPP gas is better than LP); first you will notice the flux start to "run", then it will start to "smoke" - 90% of the time the fitting is ready for solder.
When the solder starts to run, go completely around the pipe with the solder...if/when it literally starts to run down the pipe(away from joint) your done.
I try and do both sides of 1/2 and 3/4 fittings in one heat application. I will also try and sweat as many joints in one line as possible, at a time.
Then wipe the joints down with a damp cloth - you have to remove the excess flux or it will start to corrode the pipe...you will notice old flux turns green quickly. It you have to, warm the pipe up again to get the flux running and wipe with a damp cloth.
Here's a tip:
Keep a spray bottle handy (filled with water). In the event you need to put something "out" (like a 2x4, insulation, your pant leg) a few spritzs and no worries of an actual fire. This tip may be based on my own (lack of) experience, or may have been found someplace on the web - I'll never tell
